منابع مشابه
Stepwise walden inversion in nucleophilic substitution at phosphorus.
We have studied the mechanism of S(N)2@P reactions in the model systems X(-) + PMe(2)Y and X(-) + POR(2)Y (with R=Me, OH, OMe; and X, Y=Cl, OH, MeO) using density functional theory at OLYP/TZ2P. Our main purpose is to analyze the nature of the Walden inversion in our model nucleophilic substitution reactions. Walden inversion is well-known to proceed, in general, as a concerted umbrella motion ...
متن کاملSUGAR ACETATES, HALOGENO-ACETATES, AND ORTHOESTERS IN RELATION TO THg WALDEN INVERSION By
All rights reserved INFORMATION TO ALL USERS The quality of this reproduction is dependent upon the quality of the copy submitted. In the unlikely event that the author did not send a complete manuscript and there are missing pages, these will be noted. Also, if material had to be removed, a note will indicate the deletion.
متن کاملDynamical barrier and isotope effects in the simplest substitution reaction via Walden inversion mechanism
Reactions occurring at a carbon atom through the Walden inversion mechanism are one of the most important and useful classes of reactions in chemistry. Here we report an accurate theoretical study of the simplest reaction of that type: the H+CH4 substitution reaction and its isotope analogues. It is found that the reaction threshold versus collision energy is considerably higher than the barrie...
متن کاملWalden two: The morality of anarchy.
The utopian label is often pinned on calls for comprehensive change as a means of dismissing them from serious consideration.... [S]ocial orders come and go, and those who indulge in utopian thinking may be more prepared for... the inevitability of widespread societal transformation.... Keeping utopia in mind can prevent our settling for minor reforms when more significant change might be possi...
متن کاملComparing Geostatistical Seismic Inversion Based on Spectral Simulation with Deterministic Inversion: A Case Study
Seismic inversion is a method that extracts acoustic impedance data from the seismic traces. Source wavelets are band-limited, and thus seismic traces do not contain low and high frequency information. Therefore, there is a serious problem when the deterministic seismic inversion is applied to real data and the result of deterministic inversion is smooth. Low frequency component is obtained fro...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Journal of Biological Chemistry
سال: 1939
ISSN: 0021-9258
DOI: 10.1016/s0021-9258(18)73835-0